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- W2030854438 abstract "We have studied transmembrane electron transfer mediated by an amphiphilic viologen (C16,1′ V2+) in lecithin vesicles. There is no long-range electron transfer between viologens bound to opposite interfaces of the vesicle membrane, as is often proposed. Instead we proposed a mechanism where the rate-determining step is the disproportionation of two viologen radical cations (2C16,1′ V+ ⇔C16,1′ V2+ + C16,1′ V0) forming a doubly reduced, uncharged viologen that transfers electrons by rapid transmembrane diffusion and subsequent reduction of electron acceptors. Studies on other redox mediators provided further information. A brief background to the field is given, including comments on work done by others in relevant systems." @default.
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- W2030854438 date "1993-10-01" @default.
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- W2030854438 title "Electron transfer through vesicle membranes: Mechanistic ambiguities" @default.
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- W2030854438 doi "https://doi.org/10.1007/bf03040825" @default.
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