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- W2030857921 abstract "Abstract Fluorinated aryl methyl ketones have been prepared using a Friedel-Crafts reation by treating fluorinated aromatic hydrocarbons with acetyl chloride in the presence of anhydrous aluminium chloride in dry carbon disulfide. Reduction of these fluorinated aryl methyl ketones with sodiumborohydride in dry isopropanol affords 1-fluoro-1-arylethanols, which on treatment with diethylaminosulfur trifluoride (DAST) yields 1-fluoro-1-arylethane (racemic product). Studies on enantioselective reduction, followed by fluorination of 2, are in progress." @default.
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- W2030857921 date "1992-08-01" @default.
- W2030857921 modified "2023-09-24" @default.
- W2030857921 title "Selective fluorination of 1-fluoro-l-arylethanols by diethylaminosulfur trifluoride" @default.
- W2030857921 doi "https://doi.org/10.1016/s0022-1139(00)80611-9" @default.
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