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• W2030888925 abstract "Grignard reagents attack 1-imidoylbenzotriazoles at the imidoyl carbon atom and also at the benzotriazolyl N-2 and N-3 atoms leading to complex reaction mixtures, the composition of which allowed identification of the main reaction paths. Mechanisms are discussed. Previous examples of nucleophilic attack on pyridine-like nitrogen atoms are reviewed. The 1-imidoylbenzotriazoles were prepared from amides with benzotriazole and phosphoryl chloride. Amides derived from secondary amines give α-(benzotriazol-1-yl) enamines." @default.
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• W2030888925 date "1990-07-01" @default.
• W2030888925 modified "2023-10-16" @default.
• W2030888925 title "Nucleophilic Attack at Heterocyclic Nitrogen: Unusual Reactivity of the Benzotriazole Heterocyclic Ring" @default.
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• W2030888925 doi "https://doi.org/10.1002/cber.19901230715" @default.
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