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- W2030975087 abstract "The stepwise and reversible reduction of copper(II) ions in supporting electrolytes consisting of 0.5–4.0 M sodium azide at constant ionic strength was studied ; the behavior was different from that observed in thiocyanate solutions. The diffusion current constant for the sum of the two waves, in 4.0 M sodium azide supporting electrolyte, is 2.62 and is exactly twice the value for the first wave. The maximum number of azide ligands was found to be 4 and 3 for copper(II) and copper(I), respectively. No evidence was found for polynuclear species. On examine les paliers et la réduction réversible des ions cuivre(II) dans des solution d'azoture de sodium 0.5 à 4.0 M comme électrolyte de base, à force ionique constante. Le comportement est différent de celui observé dans des solutions au thiocyanate. Le courant de diffusion, constant pour la somme des deux vagues, dans l'azoture de sodium 4.0 M est de 2.62; il est exactement le double de la valeur du premier palier. Le nombre maximum de ligands azoture est de 4 pour le cuivre(II) et 3 pour le cuivre(I). On n'a pas de preuve de la présence de groupes polynucléaires. Es wurde die schrittweise, reversible Reduktion von Kupfer(II)-Ionen in Trägerelektrolyten mit 0.5–4.0 M Natriumazid bei konstanter Ionenstärke untersucht. Das Verhalten unterschied sich von demjenigen, welches in Thiocyanatlösungen beobachtet wurde. Die Diffusionstromkonstante für die Summe zweier Stufen in 4.0 M Natriumazid beträgt 2.62 und ist genau doppelt so gross wie für die I. Stufe. Die maximale Zahl der Azid-Liganden beträgt für Kupfer(II) vier und Kupfer(I) drei. Anzeichen für polynukleare Spezies wurden nicht gefunden." @default.
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- W2030975087 date "1969-11-01" @default.
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- W2030975087 title "Polarographic characteristics of copper ions in azide solutions" @default.
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- W2030975087 doi "https://doi.org/10.1016/s0003-2670(01)85256-9" @default.
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