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- W2030994018 abstract "By heating aryl aldehydes with catalytic amounts of a rhenium complex, ReBr(CO)5, and N-phenylacetamide in toluene, indenone derivatives are obtained in good to excellent yields. This reaction proceeds via (1) the formation of an isobenzofuran derivative by the insertion of an aldehyde into the C−H bond of another aldehyde (C−H bond activation) and successive intramolecular nucleophilic cyclization, (2) nucleophilic addition of the formed isobenzofuran derivative to the third aldehyde, (3) isomerization, and (4) intramolecular aldol condensation." @default.
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- W2030994018 date "2010-06-07" @default.
- W2030994018 modified "2023-10-16" @default.
- W2030994018 title "Rhenium-Catalyzed Synthesis of Indenones by Novel Dehydrative Trimerization of Aryl Aldehydes via C−H Bond Activation" @default.
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- W2030994018 doi "https://doi.org/10.1021/ol100947p" @default.
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