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• W2031002735 startingPage "10256" @default.
• W2031002735 abstract "The synthesis of the fully fluorinated bis-anilido ligand N,N'-bis-pentafluorophenyl-3,4,5,6-tetrafluorophenylene-1,2-diamine, 1 is described. Reaction of one or two equivalents of 1 with AlMe(3) gives aluminium compounds incorporating one or two ligands, the latter being the protonated form of a new weakly coordinating anion (WCA), 3-H. Alternatively, reaction of 1 with LiAlH(4) yields the lithium salt of this anion, 3-Li, which may be employed as a reagent for preparing the trityl and N,N-dimethylanilinium salts of the aluminate anion. All ion pairs are fully characterized and the use of 3-Ph(3)C to generate titanium-based alkyl cations is also described." @default.
• W2031002735 created "2016-06-24" @default.
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• W2031002735 date "2010-01-01" @default.
• W2031002735 modified "2023-09-26" @default.
• W2031002735 title "A new weakly coordinating aluminate anion incorporating a chelating perfluoro-bis-anilido ligand" @default.
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• W2031002735 doi "https://doi.org/10.1039/c0dt00846j" @default.
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