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- W2031008027 abstract "The NMR spectra of sodium dodecyl sulfate (SDS) solutions and of Brij 35 solutions were examined in the presence of benzyl alcohol, 2-phenylethanol, 3-phenylpropanol, or 2-phenylethylamine. The signal of the methylene chain in SDS split into an up-field signal and a down-field signal with broadening. The addition of 3-phenylpropanol produced a down-field shift of the methyl signal of SDS, and the addition of 2-phenylethylamine produced not only a down-field shift of the methyl signal but also a down-field shift of the inner methylenes in SDS. The other signals were up-field shifted by the addition of the phenyl derivatives. The signal of the methylene chain was resolved into three peaks (I, II, III) by a computer simulation method. Peak I was assigned to the methylene groups close in the β-methylene of the surfactant. It was concluded that the phenyl alcohol was solubilized with its polar head near the micelle surface and with the phenyl group in the region of the middle methylenes of the micelle. In the Brij 35 solutions, the solubilization site of the alcohol varied gradually from the polyoxyethylene mantle of the micelle to its inner hydrocarbon region with increasing size of the alcohol." @default.
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- W2031008027 date "1980-11-01" @default.
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- W2031008027 title "NMR study about solubilization of phenyl alkyl alcohol in sodium dodecyl sulfate micelle and in Brij 35 micelle" @default.
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- W2031008027 doi "https://doi.org/10.1016/0021-9797(80)90507-x" @default.
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