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- W2031011520 abstract "Action of some nucleophilic reagents (CH 3 COOAg, CH 3 COOK, LiAlH 4 ) on 6β-chloro- and 6β-methanesulfonyloxy-5-methyl-19-nor-5β-cholest-9-enes VIII - XII affords predominantly A-homo-B,19-dinor-5β-cholest-9-ene derivatives, arising by rearrangement and substitution ( XIII, XXIV ) or rearrangement and elimination ( e.g. XX ). Hydrogenolysis of compounds of the type VIII with lithium aluminium hydride gives, in addition, a product of rearrangement, fragmentation and further reduction ( XXVI ), and 5-methyl-6α,10-cyclo-19-nor-5β,9β,10α-cholestan-3β-ol ( XXX )." @default.
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- W2031011520 date "1986-01-01" @default.
- W2031011520 modified "2023-09-24" @default.
- W2031011520 title "Solvolysis of Westphalen-type compounds" @default.
- W2031011520 doi "https://doi.org/10.1135/cccc19861462" @default.
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