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- W2031031832 abstract "Die Methoxid-katalysierte Umlagerung von Grevillin-Derivaten 2 liefert Terphenylchinone 1 in hohen Ausbeuten. Die Flexibilität dieser Methode wird an der Synthese von Polyporsäure (1a), Ascocorynin (1b) und Leucomelon (1m) demonstriert, sowie von Terphenylchinonen und Terphenylchinon-Analogen, die 2,4,5-Trihydroxyphyenyl-, 4-Nitrophenyl-, 2,4-Dichlorphenyl-, Naphthyl-, Indolyl- und Styryl-Reste enthalten. Die so dargestellten Verbindungen 1 lassen sich nach Wikholm und Moore(20) in Pulvinsäurelactone 6 umwandeln. Fungal Pigments, 501). – Synthesis of Terphenylquinones via Methoxide-catalyzed Rearrangement of Grevillin Derivatives The methoxide-catalyzed rearrangement of grevillin derivatives 2 affords terphenylquinones 1 in high yields. The flexibility of this approach is demonstrated by the synthesis of polyporic acid (1a), ascocorynin (1b), and leucomelone (1m) as well as of terphenylquinones or its analogues which contain 2,4,5-trihydroxyphenyl, 4-nitrophenyl, 2,4-dichlorophenyl, naphthyl, indolyl, and styryl residues. These compounds may be converted into pulvinic acid lactones 6 by Wikholm and Moore′s(20) procedure." @default.
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- W2031031832 date "1986-01-14" @default.
- W2031031832 modified "2023-10-16" @default.
- W2031031832 title "Pilzfarbstoffe, 501) Synthese von Terphenylchinonen durch Methoxid-katalysierte Umlagerung von Grevillin-Derivaten" @default.
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- W2031031832 doi "https://doi.org/10.1002/jlac.198619860117" @default.
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