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- W2031032361 abstract "A salicylate PVC-based membrane (SPME) and a coated graphite membrane (SCGE) electrodes by using a new tetracoordinate organonickel complex as ion carrier were prepared. Both sensors show a Nernstian response to salicylate ions over a very wide concentration ranges (1.0×10−5–1.0×10−1 M for SPME and 1.0×10−6–1.0×10−2 M for SCGE) in the pH of 7.0. The best selectivities were obtained for the membrane incorporating 30% PVC, 63% plasticizer, 2% cationic additive and 5% ionophore. The electrodes possess satisfactory reproducibility, very short response time (∼10 s) in the whole concentration ranges, and excellent discriminating ability for salicylate ions with respect to the most common organic and inorganic anions. The detection limits of proposed sensors are 5.0×10−6 and 7.0×10−7 M for SPME and SCGE, respectively. The electrodes were successfully used for determination of salicylate in biological samples." @default.
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- W2031032361 date "2003-11-04" @default.
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- W2031032361 title "Bis (trans-cinnamaldehyde) ethylene diimine dibromonickel (II) complex as a neutral carrier for salicylate-selective liquid membrane and coated graphite sensors" @default.
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- W2031032361 doi "https://doi.org/10.1016/s0039-9140(03)00273-x" @default.
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