Matches in SemOpenAlex for { <https://semopenalex.org/work/W2031032393> ?p ?o ?g. }
Showing items 1 to 78 of
78
with 100 items per page.
- W2031032393 endingPage "3036" @default.
- W2031032393 startingPage "3032" @default.
- W2031032393 abstract "We present the formation, structure and properties of a new family of molecular crystals of distinct rotating and static components: the derivatives of fullerenes with cubane. The new crystals consist of alternating arrays of the constituents, stabilized by the recognition of the complementary molecular surfaces. The concave cubanes match six rotating fullerenes in octahedral configuration, while the six nearest neighbours of the convex fullerenes may form either octahedral or trigonal prismatic configurations. Fullerenes rotate freely in the ‘molecular bearing’ of cubanes. Lower symmetry crystals of similar properties form when cubane is replaced by 1,4-diethynyl cubane. The following properties will be discussed: (i) The significant size and shape recognition makes possible the design of the crystal structure of new higher fullerenes and substituted cubane derivatives. (ii) The phase diagram of the rotor–stator crystals can be constructed in terms of the ball diameter of rotating fullerenes. (iii) The molecular geometry of the constituents has an influence on the structure and dynamics of the lower symmetry variants. (iv) At elevated temperatures the decomposition of cubane or diethynyl cubane induces topochemical copolymerization with the surrounding fullerenes. (© 2006 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim)" @default.
- W2031032393 created "2016-06-24" @default.
- W2031032393 creator A5005363372 @default.
- W2031032393 creator A5006322117 @default.
- W2031032393 creator A5026089586 @default.
- W2031032393 creator A5029364119 @default.
- W2031032393 creator A5033226027 @default.
- W2031032393 creator A5048407842 @default.
- W2031032393 creator A5050739630 @default.
- W2031032393 creator A5055924639 @default.
- W2031032393 creator A5060586012 @default.
- W2031032393 creator A5066757677 @default.
- W2031032393 creator A5070440363 @default.
- W2031032393 date "2006-11-01" @default.
- W2031032393 modified "2023-10-18" @default.
- W2031032393 title "Rotor–stator phases of fullerenes with cubane derivatives: A novel family of heteromolecular crystals" @default.
- W2031032393 cites W11476871 @default.
- W2031032393 cites W2010053818 @default.
- W2031032393 cites W2051940035 @default.
- W2031032393 cites W2064062891 @default.
- W2031032393 cites W2094979510 @default.
- W2031032393 cites W2139896881 @default.
- W2031032393 cites W4249003676 @default.
- W2031032393 doi "https://doi.org/10.1002/pssb.200669136" @default.
- W2031032393 hasPublicationYear "2006" @default.
- W2031032393 type Work @default.
- W2031032393 sameAs 2031032393 @default.
- W2031032393 citedByCount "13" @default.
- W2031032393 countsByYear W20310323932020 @default.
- W2031032393 crossrefType "journal-article" @default.
- W2031032393 hasAuthorship W2031032393A5005363372 @default.
- W2031032393 hasAuthorship W2031032393A5006322117 @default.
- W2031032393 hasAuthorship W2031032393A5026089586 @default.
- W2031032393 hasAuthorship W2031032393A5029364119 @default.
- W2031032393 hasAuthorship W2031032393A5033226027 @default.
- W2031032393 hasAuthorship W2031032393A5048407842 @default.
- W2031032393 hasAuthorship W2031032393A5050739630 @default.
- W2031032393 hasAuthorship W2031032393A5055924639 @default.
- W2031032393 hasAuthorship W2031032393A5060586012 @default.
- W2031032393 hasAuthorship W2031032393A5066757677 @default.
- W2031032393 hasAuthorship W2031032393A5070440363 @default.
- W2031032393 hasConcept C115624301 @default.
- W2031032393 hasConcept C159467904 @default.
- W2031032393 hasConcept C162862793 @default.
- W2031032393 hasConcept C178790620 @default.
- W2031032393 hasConcept C185592680 @default.
- W2031032393 hasConcept C198819137 @default.
- W2031032393 hasConcept C2780750454 @default.
- W2031032393 hasConcept C8010536 @default.
- W2031032393 hasConceptScore W2031032393C115624301 @default.
- W2031032393 hasConceptScore W2031032393C159467904 @default.
- W2031032393 hasConceptScore W2031032393C162862793 @default.
- W2031032393 hasConceptScore W2031032393C178790620 @default.
- W2031032393 hasConceptScore W2031032393C185592680 @default.
- W2031032393 hasConceptScore W2031032393C198819137 @default.
- W2031032393 hasConceptScore W2031032393C2780750454 @default.
- W2031032393 hasConceptScore W2031032393C8010536 @default.
- W2031032393 hasIssue "13" @default.
- W2031032393 hasLocation W20310323931 @default.
- W2031032393 hasOpenAccess W2031032393 @default.
- W2031032393 hasPrimaryLocation W20310323931 @default.
- W2031032393 hasRelatedWork W167857991 @default.
- W2031032393 hasRelatedWork W1969215021 @default.
- W2031032393 hasRelatedWork W1969352129 @default.
- W2031032393 hasRelatedWork W1975533112 @default.
- W2031032393 hasRelatedWork W2032904027 @default.
- W2031032393 hasRelatedWork W2039836026 @default.
- W2031032393 hasRelatedWork W2074779033 @default.
- W2031032393 hasRelatedWork W2316937681 @default.
- W2031032393 hasRelatedWork W2324887520 @default.
- W2031032393 hasRelatedWork W2950083354 @default.
- W2031032393 hasVolume "243" @default.
- W2031032393 isParatext "false" @default.
- W2031032393 isRetracted "false" @default.
- W2031032393 magId "2031032393" @default.
- W2031032393 workType "article" @default.