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- W2031034791 endingPage "1995" @default.
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- W2031034791 abstract "Flash vacuum pyrolysis of the ester 1,3,4,5,6,7,8-heptafluoro-2-naphthyl propynoate (6) at 550 °C/0.01 mmHg gave three products: 3 and 4 by an overall decarbonylation reaction, and 5 by a further decarbonylation of 3 and/or 4. Isomerisation of 6 to 2-fluoropropynyl 2-naphthoate 8 by a Diels–Alder/retro-Diels-Alder sequence followed by decarbonylation and a series of 1,2-fluorine shifts offers a rationalisation for the formation of the products." @default.
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- W2031034791 date "1994-01-01" @default.
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- W2031034791 title "The pyrolysis of 1,3,4,5,6,7,8-heptafluoro-2-naphthyl propynoate: remarkable products obtained via an internal Diels–Alder reaction" @default.
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- W2031034791 doi "https://doi.org/10.1039/p19940001991" @default.
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