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- W2031036221 abstract "Abstract Silylphosphines R 3 SiPR′ 2 add on the CN group of aldimines yielding phosphinylated silylamines of the structure . Hydrolysis of these adducts leads to the corresponding substituted aminomethyl‐phosphines. In the reaction between α‐diimines and silylphosphines or silyldiphosphines R 2 Si(PR′ 2 ) 2 the acyclic 1/1 and ½ addition compounds have been characterized. The adduct 1/1 obtained by the action of diethyl‐hydrodimethylsilyl‐phosphine on di‐tert‐butylimino‐ethane undergoes in the presence of Wilkinson's catalyst, (Ph 3 P) 3 RhCl, an intramolecular Si‐H/CN cyclisation leading to a phosphinylated siladiazolidine. Silylphosphines add to N‐acylimines in 1,4 position to form phosphinylated siloxyimines. The methanolysis of the latter derivatives is an novel method of preparation of phosphinylated amides. Silyl‐ and germylphosphines react on the CN groupement of cetimines. The hydrolysis of the adducts (N‐metallated enamines) leads to C‐phosphinylated imines." @default.
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- W2031036221 date "1975-07-16" @default.
- W2031036221 modified "2023-10-17" @default.
- W2031036221 title "Réactivité des silyl- et germylphosphines vis-à-vis de divers composés à insaturation CN: imines, α-diimines, N-acylimines et cétènimines" @default.
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- W2031036221 doi "https://doi.org/10.1002/hlca.19750580510" @default.
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