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• W2031079534 abstract "High-resolution excitation spectra of some NO2 bands around λ = 592.5 nm have been taken with a linewidth down to 10 MHz. The experimental arrangement consists of a collimated supersonic NO2 beam crossed perpendicularly with the beam of a tunable single-mode dye laser. The wavelengths of the NO2 lines were measured with a “Lambdameter” of the Michelson-type with an absolute accuracy of 10−3 cm−1. The analysis of a K−1 = 0 subband showed strong anomalies of the spin splittings in the upper 2B2 state. It was possible to fit the completely resolved hyperfine structure splittings of most lines with a standard deviation of less than 5 MHz, although a few transitions showed significant perturbations. Possible causes of perturbations for fine-structure splittings are discussed. The analysis yields some molecular constants for the 2B2 state. The ground-state splittings obtained from this work agree with the infrared and microwave results." @default.
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• W2031079534 date "1981-07-01" @default.
• W2031079534 modified "2023-09-24" @default.
• W2031079534 title "Sub-Doppler laser spectroscopy of NO2 in the λ = 592.5-nm region" @default.
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• W2031079534 doi "https://doi.org/10.1016/0022-2852(81)90358-1" @default.
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