FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2031082007> ?p ?o ?g. }

• W2031082007 endingPage "2644" @default.
• W2031082007 startingPage "2637" @default.
• W2031082007 abstract "The synthesis and structural characterization of the complex Ru2(CN)(μ-DPhF)4 (1) (DPhF=N,N′-diphenylformamidinate) is reported. The reactivity of the axial position of Ru2Cl(μ-O2CMe)(μ-DPhF)3 is studied and the crystal structures of Ru2(N3)(μ-O2CMe)(μ-DPhF)3 (2) and Ru2(NCS)(μ-O2CMe)(μ-DPhF)3 (3) are described. The isolation of Ru2Cl(μ-N3Ph2)4 (4) and Ru2Cl2(μ-N3Ph2)4 (5), and the crystal structure determination of complex 4, which constitutes the first example of a chlorotriazenido derivative, are also reported. Each complex forms discrete dinuclear molecules in the solid state, having (each diruthenium unit) one free axial position. The shortest Ru–Ru distance [2.286(2) Å] is observed in the cyano derivative (1) and the longest [2.4747(11) Å] is found in the triazenido complex (4). The azido (2) and isothiocyanato (3) derivatives show similar Ru–Ru distances of 2.3182(11) and 2.3159(4) Å, respectively. Complexes 2 and 4 display magnetic moments at room temperature corresponding to three unpaired electrons in agreement with the σ2π4δ2(π∗δ∗)3 ground-state configuration, whereas compounds 1 and 3 are low spin complexes with only one unpaired electron. Only very few examples of low spin diruthenium(II,III) species have been previously characterized. The diruthenium(III) compound 5 is diamagnetic." @default.
• W2031082007 created "2016-06-24" @default.
• W2031082007 creator A5004477332 @default.
• W2031082007 creator A5016376750 @default.
• W2031082007 creator A5019732428 @default.
• W2031082007 creator A5037316104 @default.
• W2031082007 creator A5065341738 @default.
• W2031082007 creator A5069483283 @default.
• W2031082007 creator A5084792068 @default.
• W2031082007 creator A5089657251 @default.
• W2031082007 date "2004-11-01" @default.
• W2031082007 modified "2023-10-18" @default.
• W2031082007 title "Synthesis and crystal structure of high and low spin diruthenium complexes with diphenylformamidine and diphenyltriazene ligands" @default.
• W2031082007 cites W1979222665 @default.
• W2031082007 cites W1980692969 @default.
• W2031082007 cites W1997133305 @default.
• W2031082007 cites W2005530692 @default.
• W2031082007 cites W2007251954 @default.
• W2031082007 cites W2013404865 @default.
• W2031082007 cites W2014855009 @default.
• W2031082007 cites W2020247738 @default.
• W2031082007 cites W2040071823 @default.
• W2031082007 cites W2041859473 @default.
• W2031082007 cites W2042624032 @default.
• W2031082007 cites W2043127396 @default.
• W2031082007 cites W2044582351 @default.
• W2031082007 cites W2051898940 @default.
• W2031082007 cites W2061370482 @default.
• W2031082007 cites W2064730738 @default.
• W2031082007 cites W2074510696 @default.
• W2031082007 cites W2077041999 @default.
• W2031082007 cites W2079258511 @default.
• W2031082007 cites W2081309796 @default.
• W2031082007 cites W2083240081 @default.
• W2031082007 cites W2084087831 @default.
• W2031082007 cites W2091305664 @default.
• W2031082007 cites W2095014715 @default.
• W2031082007 cites W2313602266 @default.
• W2031082007 cites W2318411184 @default.
• W2031082007 cites W2440265177 @default.
• W2031082007 doi "https://doi.org/10.1016/j.poly.2004.05.015" @default.
• W2031082007 hasPublicationYear "2004" @default.
• W2031082007 type Work @default.
• W2031082007 sameAs 2031082007 @default.
• W2031082007 citedByCount "37" @default.
• W2031082007 countsByYear W20310820072013 @default.
• W2031082007 countsByYear W20310820072014 @default.
• W2031082007 countsByYear W20310820072015 @default.
• W2031082007 countsByYear W20310820072016 @default.
• W2031082007 countsByYear W20310820072017 @default.
• W2031082007 countsByYear W20310820072018 @default.
• W2031082007 countsByYear W20310820072019 @default.
• W2031082007 countsByYear W20310820072020 @default.
• W2031082007 countsByYear W20310820072021 @default.
• W2031082007 countsByYear W20310820072022 @default.
• W2031082007 crossrefType "journal-article" @default.
• W2031082007 hasAuthorship W2031082007A5004477332 @default.
• W2031082007 hasAuthorship W2031082007A5016376750 @default.
• W2031082007 hasAuthorship W2031082007A5019732428 @default.
• W2031082007 hasAuthorship W2031082007A5037316104 @default.
• W2031082007 hasAuthorship W2031082007A5065341738 @default.
• W2031082007 hasAuthorship W2031082007A5069483283 @default.
• W2031082007 hasAuthorship W2031082007A5084792068 @default.
• W2031082007 hasAuthorship W2031082007A5089657251 @default.
• W2031082007 hasConcept C106159729 @default.
• W2031082007 hasConcept C111771559 @default.
• W2031082007 hasConcept C115260700 @default.
• W2031082007 hasConcept C115624301 @default.
• W2031082007 hasConcept C121332964 @default.
• W2031082007 hasConcept C142724271 @default.
• W2031082007 hasConcept C161790260 @default.
• W2031082007 hasConcept C162324750 @default.
• W2031082007 hasConcept C178790620 @default.
• W2031082007 hasConcept C184779094 @default.
• W2031082007 hasConcept C185592680 @default.
• W2031082007 hasConcept C186927785 @default.
• W2031082007 hasConcept C204787440 @default.
• W2031082007 hasConcept C2776910235 @default.
• W2031082007 hasConcept C32909587 @default.
• W2031082007 hasConcept C55493867 @default.
• W2031082007 hasConcept C555196967 @default.
• W2031082007 hasConcept C62520636 @default.
• W2031082007 hasConcept C69523127 @default.
• W2031082007 hasConcept C71240020 @default.
• W2031082007 hasConcept C71924100 @default.
• W2031082007 hasConcept C8010536 @default.
• W2031082007 hasConcept C96026104 @default.
• W2031082007 hasConceptScore W2031082007C106159729 @default.
• W2031082007 hasConceptScore W2031082007C111771559 @default.
• W2031082007 hasConceptScore W2031082007C115260700 @default.
• W2031082007 hasConceptScore W2031082007C115624301 @default.
• W2031082007 hasConceptScore W2031082007C121332964 @default.
• W2031082007 hasConceptScore W2031082007C142724271 @default.
• W2031082007 hasConceptScore W2031082007C161790260 @default.
• W2031082007 hasConceptScore W2031082007C162324750 @default.
• W2031082007 hasConceptScore W2031082007C178790620 @default.
• W2031082007 hasConceptScore W2031082007C184779094 @default.
• W2031082007 hasConceptScore W2031082007C185592680 @default.

• next