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- W2031088729 abstract "The Ba2+2H+ ion exchange process has been studied, and exchange isotherms and titration curves have been obtained at 25.0, 40.0 and 55.0°C (± 0.1°C). The γ-Ti(Ba0.5HPO4)(PO4) · 1.5H2O phase was formed by using BaCl2 and HCl solutions. Equilibrium constants, free energy, enthalpy and entropy of the exchange reaction were determined. The barium half-exchanged phase loses water stepwise at progressively higher temperatures until it becomes anhydrous. At 900°C a mixture of two crystalline solid phases (BaTiP2O8 and α-TiP2O7) is obtained. The results are compared with those obtained by decomposition of the γ-Ti(Ca0.37H1.25PO4)(PO4 · 3.5H2O phase at 900°C, which produces a mixture of CaTi4(PO4)6, Ca3(PO4)2 and α-TiP2O7 phases." @default.
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- W2031088729 date "1995-01-01" @default.
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- W2031088729 title "Barium titanium phosphates: Ba2+2H+ ion exchange in γ-titanium phosphate and thermal behaviour of barium and calcium exchanged phases" @default.
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- W2031088729 doi "https://doi.org/10.1016/0040-6031(95)90724-6" @default.
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