Matches in SemOpenAlex for { <https://semopenalex.org/work/W2031136025> ?p ?o ?g. }
Showing items 1 to 90 of
90
with 100 items per page.
- W2031136025 endingPage "114" @default.
- W2031136025 startingPage "105" @default.
- W2031136025 abstract "The cross-polarization magic angle spinning 13C NMR spectra of Hg(SbF6)2 - 2 Arene (Arene = C6HMe5, 1,2,4,5-C6H2Me4, 1,2,3,4-C6H2Me4, or C6H6) have been measured. The spectra of the complexes of C6HMe5 and 1,2,4,5-C6H2Me4 are consistent with static η1-bonding of the mercury to the arene at an unsubstituted carbon atom, while the spectra of the 1,2,3,4-C6H2Me4 and C6H6 complexes show the arene to have time-averaged Cs or C2, and C6 symmetry respectively, at the temperature of measurement (300 K). The reduced temperature 13C NMR spectra of Hg(Arene)n2+ (n = 1 or 2; Arene = 1,3,5-C6H3R3 (R = Me, i-Pr, or t-Bu)) in SO2 solution are also reported and affirm that in these intramolecularly mobile species the mercury bonds in an η1-manner, with unsubstituted aryl carbon atoms being the strongly preferred point of mercury attachment. This site preference is further demonstrated by the solution 13C NMR spectra of Hg(Arene)n2+ (Arene = 1,2,3,4-C6H2-Me4, n = 1 or 2; Arene = 1,4-C6H4R2, R = Me or t-Bu, n = 1). The spectra of the 1,4-C6H4R2 complexes and Hg(p-C6H4-t-BuMe)2+ provide clear evidence for steric influence of the binding site. Like Hg(C6Me6)22+, but unlike most of the complexes of substituted benzenes which have been studied, Hg(1,3,5-C6H3-i-Pr3)22+ exchanges only slowly with excess free ligand." @default.
- W2031136025 created "2016-06-24" @default.
- W2031136025 creator A5029830311 @default.
- W2031136025 creator A5035999724 @default.
- W2031136025 creator A5040405782 @default.
- W2031136025 creator A5069925780 @default.
- W2031136025 date "1982-02-01" @default.
- W2031136025 modified "2023-10-16" @default.
- W2031136025 title "The solid state structure of arene-mercury(II) complexes from magic-angle spinning carbon-13 NMR and the solution carbon-13 NMR of some complexes of mercury(II) with arenes having bulky aliphatic substituents" @default.
- W2031136025 cites W1494651695 @default.
- W2031136025 cites W1968957317 @default.
- W2031136025 cites W1971028188 @default.
- W2031136025 cites W1981352057 @default.
- W2031136025 cites W2006323851 @default.
- W2031136025 cites W2011800891 @default.
- W2031136025 cites W2069521063 @default.
- W2031136025 cites W2082880032 @default.
- W2031136025 cites W2952178250 @default.
- W2031136025 cites W3005252982 @default.
- W2031136025 cites W3005301591 @default.
- W2031136025 doi "https://doi.org/10.1016/s0022-328x(00)87426-4" @default.
- W2031136025 hasPublicationYear "1982" @default.
- W2031136025 type Work @default.
- W2031136025 sameAs 2031136025 @default.
- W2031136025 citedByCount "19" @default.
- W2031136025 countsByYear W20311360252015 @default.
- W2031136025 crossrefType "journal-article" @default.
- W2031136025 hasAuthorship W2031136025A5029830311 @default.
- W2031136025 hasAuthorship W2031136025A5035999724 @default.
- W2031136025 hasAuthorship W2031136025A5040405782 @default.
- W2031136025 hasAuthorship W2031136025A5069925780 @default.
- W2031136025 hasConcept C121332964 @default.
- W2031136025 hasConcept C1276947 @default.
- W2031136025 hasConcept C153202636 @default.
- W2031136025 hasConcept C163111631 @default.
- W2031136025 hasConcept C178790620 @default.
- W2031136025 hasConcept C185592680 @default.
- W2031136025 hasConcept C199360897 @default.
- W2031136025 hasConcept C201194858 @default.
- W2031136025 hasConcept C2777777548 @default.
- W2031136025 hasConcept C2780263894 @default.
- W2031136025 hasConcept C2781076698 @default.
- W2031136025 hasConcept C41008148 @default.
- W2031136025 hasConcept C46141821 @default.
- W2031136025 hasConcept C4839761 @default.
- W2031136025 hasConcept C66974803 @default.
- W2031136025 hasConcept C67787023 @default.
- W2031136025 hasConcept C71240020 @default.
- W2031136025 hasConcept C8010536 @default.
- W2031136025 hasConcept C84935128 @default.
- W2031136025 hasConceptScore W2031136025C121332964 @default.
- W2031136025 hasConceptScore W2031136025C1276947 @default.
- W2031136025 hasConceptScore W2031136025C153202636 @default.
- W2031136025 hasConceptScore W2031136025C163111631 @default.
- W2031136025 hasConceptScore W2031136025C178790620 @default.
- W2031136025 hasConceptScore W2031136025C185592680 @default.
- W2031136025 hasConceptScore W2031136025C199360897 @default.
- W2031136025 hasConceptScore W2031136025C201194858 @default.
- W2031136025 hasConceptScore W2031136025C2777777548 @default.
- W2031136025 hasConceptScore W2031136025C2780263894 @default.
- W2031136025 hasConceptScore W2031136025C2781076698 @default.
- W2031136025 hasConceptScore W2031136025C41008148 @default.
- W2031136025 hasConceptScore W2031136025C46141821 @default.
- W2031136025 hasConceptScore W2031136025C4839761 @default.
- W2031136025 hasConceptScore W2031136025C66974803 @default.
- W2031136025 hasConceptScore W2031136025C67787023 @default.
- W2031136025 hasConceptScore W2031136025C71240020 @default.
- W2031136025 hasConceptScore W2031136025C8010536 @default.
- W2031136025 hasConceptScore W2031136025C84935128 @default.
- W2031136025 hasIssue "2" @default.
- W2031136025 hasLocation W20311360251 @default.
- W2031136025 hasOpenAccess W2031136025 @default.
- W2031136025 hasPrimaryLocation W20311360251 @default.
- W2031136025 hasRelatedWork W1540558001 @default.
- W2031136025 hasRelatedWork W2009650141 @default.
- W2031136025 hasRelatedWork W2015065016 @default.
- W2031136025 hasRelatedWork W2080145570 @default.
- W2031136025 hasRelatedWork W2083892286 @default.
- W2031136025 hasRelatedWork W2117417235 @default.
- W2031136025 hasRelatedWork W2161198487 @default.
- W2031136025 hasRelatedWork W4296041754 @default.
- W2031136025 hasRelatedWork W4296089572 @default.
- W2031136025 hasRelatedWork W4307386497 @default.
- W2031136025 hasVolume "226" @default.
- W2031136025 isParatext "false" @default.
- W2031136025 isRetracted "false" @default.
- W2031136025 magId "2031136025" @default.
- W2031136025 workType "article" @default.