FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2031140112> ?p ?o ?g. }

• W2031140112 endingPage "4757" @default.
• W2031140112 startingPage "4752" @default.
• W2031140112 abstract "The combination of zerovalent metal with a catalytic second metal ion (bimetallic materials) to enhance the dechlorination efficiency and rate of chlorinated compounds has received much attention. Bimetallic materials not only enhance the dechlorination process but also alter the reduction pathway and product distribution. In this study, the efficiency and rate of tetrachloroethylene (PCE) dechlorination by metal-modified zerovalent silicon was investigated as a potential reductant for chlorinated hydrocarbons under anoxic conditions. The X-ray photoelectron spectroscopic (XPS) results showed that metal ions including Ni(II), Cu(II), and Fe(II) could be reduced to their zerovalent forms on the Si surface. The dechlorination of PCE obeyed the pseudo-first-order kinetics, and the pseudo-first-order rate constants (k(obs)) for PCE dechlorination followed the order Ni/Si > Fe/Si > Cu/Si. Addition of Cu(II) lowered the dechlorination efficiency and rate of PCE by Si, while the k(obs) values for PCE dechlorination in the presence of 0.1 mM Fe(II) and Ni(II) were 1.5-3.8 times higher than that by Si alone. In addition, the efficiency and rate of PCE dechlorination increased upon increasing the mass loading of Ni(II) ranging between 0.05 and 0.5 mM and then decreased when the Ni(II) loading was further increased to 1 mM. The scanning electron microscopic (SEM) images and electron probe microanalytical (EPMA) maps showed that the Ni nanoparticles deposited on the Si surface and aggregated to a large particle at 1 mM Ni(II), which clearly depicts that the Ni(II) loading of 0.5 mM is the optimal value to enhance the efficiency and rate of PCE dechlorination by Si. Also, the reaction pathways for PCE dechlorination changed from hydrogenolysis in the absence of Ni(II) to hydrodechlorination when Ni(II) concentrations were higher than 0.05 mM. Results obtained in this study reveal that the metal-deposited zerovalent silicon can serve as an environmentally friendly reductant for the enhanced degradation of chlorinated hydrocarbons for long-term performance." @default.
• W2031140112 created "2016-06-24" @default.
• W2031140112 creator A5014552415 @default.
• W2031140112 creator A5062100178 @default.
• W2031140112 date "2008-05-30" @default.
• W2031140112 modified "2023-10-17" @default.
• W2031140112 title "Dechlorination of Tetrachloroethylene in Aqueous Solutions Using Metal-Modified Zerovalent Silicon" @default.
• W2031140112 cites W1562013959 @default.
• W2031140112 cites W1970005467 @default.
• W2031140112 cites W1973242502 @default.
• W2031140112 cites W1973794688 @default.
• W2031140112 cites W1987665802 @default.
• W2031140112 cites W1988845564 @default.
• W2031140112 cites W1988856168 @default.
• W2031140112 cites W1995158198 @default.
• W2031140112 cites W2002210777 @default.
• W2031140112 cites W2002409092 @default.
• W2031140112 cites W2003036290 @default.
• W2031140112 cites W2004167111 @default.
• W2031140112 cites W2006896640 @default.
• W2031140112 cites W2009380584 @default.
• W2031140112 cites W2013977448 @default.
• W2031140112 cites W2021812737 @default.
• W2031140112 cites W2021882163 @default.
• W2031140112 cites W2023977482 @default.
• W2031140112 cites W2047805281 @default.
• W2031140112 cites W2048917977 @default.
• W2031140112 cites W2049326012 @default.
• W2031140112 cites W2050882273 @default.
• W2031140112 cites W2058275521 @default.
• W2031140112 cites W2059325924 @default.
• W2031140112 cites W2059850740 @default.
• W2031140112 cites W2062636232 @default.
• W2031140112 cites W2067489033 @default.
• W2031140112 cites W2071233300 @default.
• W2031140112 cites W2071348993 @default.
• W2031140112 cites W2071926750 @default.
• W2031140112 cites W2074671191 @default.
• W2031140112 cites W2078166687 @default.
• W2031140112 cites W2089433866 @default.
• W2031140112 cites W2091163398 @default.
• W2031140112 cites W2100032860 @default.
• W2031140112 cites W2108254051 @default.
• W2031140112 cites W2144172473 @default.
• W2031140112 doi "https://doi.org/10.1021/es071545x" @default.
• W2031140112 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/18678001" @default.
• W2031140112 hasPublicationYear "2008" @default.
• W2031140112 type Work @default.
• W2031140112 sameAs 2031140112 @default.
• W2031140112 citedByCount "36" @default.
• W2031140112 countsByYear W20311401122012 @default.
• W2031140112 countsByYear W20311401122013 @default.
• W2031140112 countsByYear W20311401122014 @default.
• W2031140112 countsByYear W20311401122015 @default.
• W2031140112 countsByYear W20311401122016 @default.
• W2031140112 countsByYear W20311401122017 @default.
• W2031140112 countsByYear W20311401122018 @default.
• W2031140112 countsByYear W20311401122019 @default.
• W2031140112 countsByYear W20311401122021 @default.
• W2031140112 crossrefType "journal-article" @default.
• W2031140112 hasAuthorship W2031140112A5014552415 @default.
• W2031140112 hasAuthorship W2031140112A5062100178 @default.
• W2031140112 hasConcept C121332964 @default.
• W2031140112 hasConcept C127413603 @default.
• W2031140112 hasConcept C138411078 @default.
• W2031140112 hasConcept C13965031 @default.
• W2031140112 hasConcept C148898269 @default.
• W2031140112 hasConcept C150394285 @default.
• W2031140112 hasConcept C157021035 @default.
• W2031140112 hasConcept C175708663 @default.
• W2031140112 hasConcept C178790620 @default.
• W2031140112 hasConcept C179104552 @default.
• W2031140112 hasConcept C184651966 @default.
• W2031140112 hasConcept C185592680 @default.
• W2031140112 hasConcept C199164860 @default.
• W2031140112 hasConcept C199289684 @default.
• W2031140112 hasConcept C2777166327 @default.
• W2031140112 hasConcept C2779404209 @default.
• W2031140112 hasConcept C2780371127 @default.
• W2031140112 hasConcept C40472508 @default.
• W2031140112 hasConcept C42360764 @default.
• W2031140112 hasConcept C43411465 @default.
• W2031140112 hasConcept C544153396 @default.
• W2031140112 hasConcept C544956773 @default.
• W2031140112 hasConcept C62520636 @default.
• W2031140112 hasConcept C93391505 @default.
• W2031140112 hasConceptScore W2031140112C121332964 @default.
• W2031140112 hasConceptScore W2031140112C127413603 @default.
• W2031140112 hasConceptScore W2031140112C138411078 @default.
• W2031140112 hasConceptScore W2031140112C13965031 @default.
• W2031140112 hasConceptScore W2031140112C148898269 @default.
• W2031140112 hasConceptScore W2031140112C150394285 @default.
• W2031140112 hasConceptScore W2031140112C157021035 @default.
• W2031140112 hasConceptScore W2031140112C175708663 @default.
• W2031140112 hasConceptScore W2031140112C178790620 @default.
• W2031140112 hasConceptScore W2031140112C179104552 @default.
• W2031140112 hasConceptScore W2031140112C184651966 @default.
• W2031140112 hasConceptScore W2031140112C185592680 @default.

• next