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- W2031141395 abstract "The title complexes [μ-(E)-4,4′-(ethene-1,2-diyl)dipyridine-κ2N:N′]bis[halotris(4-methylphenyl)tin(IV)], [Sn2(C7H7)6X2(C12H10N2)], where halo is chloro (X = Cl) and bromo (X = Br) are isostructural. In both crystals, the molecules lie on inversion centers, and there are voids of ca 80 Å3 that could, but apparently do not, accommodate water molecules. The corresponding iodo structure (X = I) is almost, but not quite, isostructural with the other two compounds; when Br is changed to I, the length of the c axis decreases by more than 1 Å and the voids are no longer large enough to accomodate any solvent molecule. The related complex [μ-(E)-4,4′-(ethene-1,2-diyl)dipyridine-κ2N:N′]bis[chlorotriphenyltin(IV)], [Sn2(C6H5)6Cl2(C12H10N2)], crystallizes in a related structure, but the molecules lie on general rather than on special positions. The molecular structures of the four complexes are similar, but the conformation of the phenyl derivative is approximately eclipsed rather than staggered." @default.
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- W2031141395 date "2003-05-10" @default.
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- W2031141395 title "Isostructural or not? Adducts of some aryltin halides with (<i>E</i>)-1,2-bis(4-pyridyl)ethene" @default.
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- W2031141395 doi "https://doi.org/10.1107/s0108270102023600" @default.
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