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• W2031142366 endingPage "085705" @default.
• W2031142366 startingPage "085705" @default.
• W2031142366 abstract "Visible light active and stable nanoporous polymeric base-crystalline TiO2 nanocomposites were solvothermally synthesized from in situ copolymerization of divinylbenzene (DVB) with 1-vinylimidazolate (VI) or 4-vinylpyridine (Py) in the presence of tetrabutyl titanate without the use of any other additives (PDVB-VI-TiO2-x, PDVB-Py-TiO2-x, where x stands for the molar ratio of TiO2 to VI or Py), which showed excellent activity with respect to catalyzing the degradation of organic pollutants of p-nitrophenol (PNP) and rhodamine-B (RhB). TEM and SEM images show that PDVB-VI-TiO2-x and PDVB-Py-TiO2-x have abundant nanopores, and TiO2 nanocrystals with a high degree of crystallinity were homogeneously embedded in the PDVB-VI-TiO2-x and PDVB-Py-TiO2-x, forming a stable 'brick-and-mortar' nanostructure. PDVB-VI and PDVB-Py supports act as the glue linking TiO2 nanocrystals to form nanopores and constraining the agglomeration of TiO2 nanocrystals. XPS spectra show evidence of unique interactions between TiO2 and basic sites in these samples. UV diffuse reflectance shows that PDVB-VI-TiO2-x and PDVB-Py-TiO2-x exhibit a unique response to visible light. Catalytic tests show that the PDVB-VI-TiO2-x and PDVB-Py-TiO2-x were active in catalyzing the degradation of PNP and RhB organic pollutants under visible light irradiation. The enhanced activities of the PDVB-VI-TiO2-x and PDVB-Py-TiO2-x were ascribed to synergistic effects between abundant nanopores and the unique optical adsorption of visible light in the samples." @default.
• W2031142366 created "2016-06-24" @default.
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• W2031142366 date "2015-02-06" @default.
• W2031142366 modified "2023-09-27" @default.
• W2031142366 title "Solvothermal synthesis of stable nanoporous polymeric bases-crystalline TiO₂ nanocomposites: visible light active and efficient photocatalysts for water treatment" @default.
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• W2031142366 doi "https://doi.org/10.1088/0957-4484/26/8/085705" @default.
• W2031142366 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/25656872" @default.
• W2031142366 hasPublicationYear "2015" @default.
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