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- W2031142400 abstract "Experimental measurement of butene-1 isomerization in the presence of low concentrations of hydrogen have demonstrated that the rate is proportional to the square root of the hydrogen partial pressure. This dependency on [H2]12 has been found to apply to palladium supported on α-alumina as well as to palladiummetal microspheres. In addition, the distribution of butene-2 isomers during the initial portion of the isomerization is of equal magnitude. These observations give further support to the addition-abstraction mechanism of hydrogen as an essential step for double-bond migration and geometrical isomerization." @default.
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- W2031142400 date "1972-02-01" @default.
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- W2031142400 title "Role of hydrogen in butene isomerization catalyzed by supported and unsupported palladium*1" @default.
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- W2031142400 doi "https://doi.org/10.1016/0021-9517(72)90075-9" @default.
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