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- W2031142775 abstract "Abstract The transition metal complex C 60 [Pd(PPh 3 ) 2 ] was prepared successfully in N 2 atmosphere free of water and oxygen and characterized by fourier transform infrared (FTIR), XPS and 13 C NMR. The catalytic conversion of 1-heptene was investigated using this new complex as the catalyst. It was found that the complex C 60 [Pd(PPh 3 ) 2 ] could actively catalyze the cyclization of 1-heptene into 1,2-dimethyl-cyclopentane. However, the complex Pd(PPh 3 ) 4 showed only the activities of hydrogenation and isomerization, instead of cyclization. It is believed that the cyclization of 1-heptene is contributing to the coordination of C 60 with Pd(PPh 3 ) 2 , but that this coordination does not arise from the mechanical mixing of C 60 and Pd(PPh 3 ) 4 ." @default.
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- W2031142775 date "1998-02-01" @default.
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- W2031142775 title "Synthesis of C60[Pd(PPh3)2] and its catalytic performance for cyclization of 1-heptene" @default.
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- W2031142775 doi "https://doi.org/10.1016/s0926-860x(97)00327-x" @default.
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