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- W2031143571 abstract "trans-Bromotetracarbonylcarbin-Komplexe Br(CO)4 WCR [R = C6H5; C6H4CH3-(4); C6H4OCH3-(4); C6H2(CH3)3-(2,4,6); C6H3-3-Br-4-OCH3; C5H4FeC5H5; N(C2H5)2] reagieren mit Cyclopentadienylnatrium unter Ersatz des Halogenliganden und zusätzlicher Abspaltung zweier CO-Gruppen zu Dicarbonyl(π-cyclopentadienyl)carbin-Komplexen des Wolframs der allgemeinen Formel π-C5H5(CO)2 WCR (1–7). Spektroskopische und physikalisch-chemische Untersuchungen derselben sowie die Röntgenstrukturanalyse von π-C5H5(CO)2 WCC6H4CH3-(4) werden mitgeteilt. Transition Metal Carbyne Complexes, XXVII. Dicarbonyl(π-cyclopentadienyl)carbyne Complexes of Tungsten trans-Bromotetracarbonylcarbyne complexes Br(CO)4 WCR [R = C6H5; C6H4CH3-(4); C6H4OCH3-(4); C6H2(CH3)3-(2,4,6); C6H3-3-Br-4-OCH3; C5H4FeC5H5; N(C2H5)2] react with cyclopentadienyl sodium, with substitution of the halogen ligand and additional elimination of two CO groups, to form dicarbonyl(π-cyclopentadienyl)carbyne complexes of tungsten of the general formula π-C5H5(CO)2 WCR (1–7). Spectroscopic and physicochemical investigations of the latter as well as an X-ray analysis of π-C5H5(CO)2 WCC6H4CH3-(4) are reported." @default.
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- W2031143571 date "1977-10-01" @default.
- W2031143571 modified "2023-09-26" @default.
- W2031143571 title "Übergangsmetall‐Carbin‐Komplexe, XXVII. Dicarbonyl(π‐cyclopentadienyl)carbin‐Komplexe des Wolframs" @default.
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- W2031143571 doi "https://doi.org/10.1002/cber.19771101019" @default.
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