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- W2031146592 abstract "The reactions of titanium(III) chloride and bromide with ammonia have been studied. No ammonolysis occurs but the following new ammoniates have been identified; TiX3·14NH3, TiX3·8NH3, TiX3·4NH3, TiX3·NH3 (X = Cl or Br) and TiBr3·5NH3. Structures for the compounds TiX3·5NH3, TiX3·4NH3, TiCl3·3NH3, TiX3, NH3 are proposed on the basis of electronic and IR spectra of these complexes and their deutero-analogues. Titanium(II) chloride is unreactive towards liquid ammonia below −20° but the bromide forms TiBr2·6NH3 at −35° which decomposes to TiBr2·4NH3 at room temperature." @default.
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- W2031146592 date "1977-01-01" @default.
- W2031146592 modified "2023-10-18" @default.
- W2031146592 title "The reactions of titanium(III) chloride and bromide and of titanium(II) chloride and bromide with ammonia" @default.
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- W2031146592 doi "https://doi.org/10.1016/0022-1902(77)80244-3" @default.
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