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- W2031153583 abstract "The kinetics of oxide-film growth on zirconium was modelled on the basis of coupled currents of cations and electrons (by both tunnelling and thermionic emission) through a homogeneous surface-charge field. Good agreement is obtained with experimental growth curves for T = 304–573 K and pO2 = 1.3 × 10−6–1.3 × 10−4 Pa. The growth rate is limited by the field-assisted cation migration in the developing oxide film. Up to oxide-film thicknesses of about 2–3 nm, a constant kinetic potential is sustained during growth by the relatively fast forward and reverse electron currents. Beyond this critical thickness for T > 473 K, the net electron flux by tunnelling drops to zero and electron transport by thermionic emission becomes rate-determining, while cation transport remains rate-limiting. Changes of the energy barrier for cation motion and of the metal–oxide and oxide–oxygen work functions are related to the transformation of the amorphous, non-stoichiometric oxide film into crystalline ZrO2." @default.
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- W2031153583 date "2005-10-01" @default.
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- W2031153583 title "The mechanism of low-temperature oxidation of zirconium" @default.
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- W2031153583 doi "https://doi.org/10.1016/j.actamat.2005.06.028" @default.
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