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- W2031161620 abstract "The asymmetric photodeconjugation of the α,β-unsaturated esters 1, 2 and 3, to the, corresponding β,γ-unsaturated esters having a new chiral center at the α position, has been studied in a variety of solvents. In most solvents, the (S)-lactyl chirnal auxiliary induced the S configuration at the new chiral center. However, irradation of 1 in methanol or 2-propanol/water mixtures gave an unusual reversal of diastereoselectivity to produce the R configuration at the new chiral center." @default.
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- W2031161620 date "1992-10-01" @default.
- W2031161620 modified "2023-10-13" @default.
- W2031161620 title "Lactate as chiral auxiliary in asymmetric photodeconjugation of unsaturated esters" @default.
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- W2031161620 doi "https://doi.org/10.1016/s0040-4039(00)60009-6" @default.
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