Matches in SemOpenAlex for { <https://semopenalex.org/work/W2031178082> ?p ?o ?g. }
Showing items 1 to 66 of
66
with 100 items per page.
- W2031178082 endingPage "183" @default.
- W2031178082 startingPage "180" @default.
- W2031178082 abstract "The original Karplus parameters for analysing 3J(POCC) magnitudes of nucleotides in terms of conformational properties of the OC bond were taken from results for 3′,5′-nucleotides and applied to 3′→ 5′-oligonucleotides; the parameters were later modified to take account of ‘largey’ magnitudes of 3J(POCC) observed in 2′ → 5′-oligonucleotides. In this work the origin of this discrepancy is explained in terms of substituent electronegativity effects at C-1′, and quantified using the 13C NMR results of 2′,3′-cyclic mononucleotides. A new set of Karplus parameters suitable for analysing 3J(POCC) magnitudes in 3′- and 5′-nucleotides and 3′ → 5′-oligonucleotides is determined from 13C NMR measurements on 3′-nucleotides and available results for 3′,5′-cyclic mononucleotides. A method of dealing with J(P, C-1′) coupling in 2′-nucleotides, 2′,3′-cyclic nucleotides and 2′ → 5′-oligonucleotides using the same Karplus relationship is suggested." @default.
- W2031178082 created "2016-06-24" @default.
- W2031178082 creator A5009535198 @default.
- W2031178082 creator A5035422400 @default.
- W2031178082 date "1982-11-01" @default.
- W2031178082 modified "2023-09-27" @default.
- W2031178082 title "On the Karplus relation for3J(POCC) of nucleotides" @default.
- W2031178082 cites W1974184192 @default.
- W2031178082 cites W1982004788 @default.
- W2031178082 cites W1990227667 @default.
- W2031178082 cites W2008252896 @default.
- W2031178082 cites W2019682747 @default.
- W2031178082 cites W2052093024 @default.
- W2031178082 cites W2090835092 @default.
- W2031178082 cites W2332600539 @default.
- W2031178082 cites W2470228578 @default.
- W2031178082 doi "https://doi.org/10.1002/mrc.1270200314" @default.
- W2031178082 hasPublicationYear "1982" @default.
- W2031178082 type Work @default.
- W2031178082 sameAs 2031178082 @default.
- W2031178082 citedByCount "16" @default.
- W2031178082 countsByYear W20311780822020 @default.
- W2031178082 crossrefType "journal-article" @default.
- W2031178082 hasAuthorship W2031178082A5009535198 @default.
- W2031178082 hasAuthorship W2031178082A5035422400 @default.
- W2031178082 hasConcept C104317684 @default.
- W2031178082 hasConcept C129312508 @default.
- W2031178082 hasConcept C177293861 @default.
- W2031178082 hasConcept C178790620 @default.
- W2031178082 hasConcept C185592680 @default.
- W2031178082 hasConcept C2778689049 @default.
- W2031178082 hasConcept C512185932 @default.
- W2031178082 hasConcept C552990157 @default.
- W2031178082 hasConcept C55493867 @default.
- W2031178082 hasConcept C71240020 @default.
- W2031178082 hasConceptScore W2031178082C104317684 @default.
- W2031178082 hasConceptScore W2031178082C129312508 @default.
- W2031178082 hasConceptScore W2031178082C177293861 @default.
- W2031178082 hasConceptScore W2031178082C178790620 @default.
- W2031178082 hasConceptScore W2031178082C185592680 @default.
- W2031178082 hasConceptScore W2031178082C2778689049 @default.
- W2031178082 hasConceptScore W2031178082C512185932 @default.
- W2031178082 hasConceptScore W2031178082C552990157 @default.
- W2031178082 hasConceptScore W2031178082C55493867 @default.
- W2031178082 hasConceptScore W2031178082C71240020 @default.
- W2031178082 hasIssue "3" @default.
- W2031178082 hasLocation W20311780821 @default.
- W2031178082 hasOpenAccess W2031178082 @default.
- W2031178082 hasPrimaryLocation W20311780821 @default.
- W2031178082 hasRelatedWork W1989692008 @default.
- W2031178082 hasRelatedWork W1995030173 @default.
- W2031178082 hasRelatedWork W2029235757 @default.
- W2031178082 hasRelatedWork W2076364111 @default.
- W2031178082 hasRelatedWork W2949568156 @default.
- W2031178082 hasRelatedWork W2950083444 @default.
- W2031178082 hasRelatedWork W2951305430 @default.
- W2031178082 hasRelatedWork W2952995821 @default.
- W2031178082 hasRelatedWork W2953298349 @default.
- W2031178082 hasRelatedWork W2964796947 @default.
- W2031178082 hasVolume "20" @default.
- W2031178082 isParatext "false" @default.
- W2031178082 isRetracted "false" @default.
- W2031178082 magId "2031178082" @default.
- W2031178082 workType "article" @default.