FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2031200134> ?p ?o ?g. }

• W2031200134 abstract "The theory developed in our earlier papers is extended to predict dynamical and thermodynamic properties of clathrate structures by accounting for the possibility of multiple filling of cavities by guest molecules. The method is applied to the thermodynamic properties of argon and krypton hydrates, considering both structures I (sI) and II (sII), in which the small cages can be singly occupied and large cages of sII can be singly or doubly occupied. It was confirmed that the structure of the clathrate hydrate is determined by two main factors: intermolecular interaction between guest and host molecules and the configurational entropy. It is shown that for guests weakly interacting with water molecules, such as argon or krypton, the free energy of host lattices without the contribution of entropy is the main structure-determining factor for clathrate hydrates, and it is a cause of hydrate sII formation at low pressure with these guests. Explicit account of the entropy contribution in the Gibbs free energy allows one to determine the stability of hydrate phases and to estimate the line of structural transition from sII to sI in P-T plane. The structural transition between sII and sI in argon and krypton hydrates at high pressure is shown to be the consequence of increasing intermolecular interaction and the degree of occupancy of the large cavities." @default.
• W2031200134 created "2016-06-24" @default.
• W2031200134 creator A5018012020 @default.
• W2031200134 creator A5035224025 @default.
• W2031200134 creator A5037329971 @default.
• W2031200134 creator A5069535376 @default.
• W2031200134 creator A5071552059 @default.
• W2031200134 creator A5077895432 @default.
• W2031200134 creator A5085354660 @default.
• W2031200134 creator A5044414244 @default.
• W2031200134 date "2009-09-18" @default.
• W2031200134 modified "2023-09-23" @default.
• W2031200134 title "Theoretical study of phase transitions in Kr and Ar clathrate hydrates from structure II to structure I under pressure" @default.
• W2031200134 cites W117063425 @default.
• W2031200134 cites W1542161271 @default.
• W2031200134 cites W1645719784 @default.
• W2031200134 cites W1970530551 @default.
• W2031200134 cites W1976481959 @default.
• W2031200134 cites W1978489598 @default.
• W2031200134 cites W2001689165 @default.
• W2031200134 cites W2004566822 @default.
• W2031200134 cites W2014826342 @default.
• W2031200134 cites W2016023716 @default.
• W2031200134 cites W2025862879 @default.
• W2031200134 cites W2037144984 @default.
• W2031200134 cites W2042440232 @default.
• W2031200134 cites W2048012970 @default.
• W2031200134 cites W2049475242 @default.
• W2031200134 cites W2051884978 @default.
• W2031200134 cites W2064674943 @default.
• W2031200134 cites W2065216847 @default.
• W2031200134 cites W2079146435 @default.
• W2031200134 cites W2090968402 @default.
• W2031200134 cites W2116742987 @default.
• W2031200134 cites W2120762878 @default.
• W2031200134 cites W2137236849 @default.
• W2031200134 cites W4253642401 @default.
• W2031200134 cites W4255806036 @default.
• W2031200134 doi "https://doi.org/10.1063/1.3212965" @default.
• W2031200134 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/19778129" @default.
• W2031200134 hasPublicationYear "2009" @default.
• W2031200134 type Work @default.
• W2031200134 sameAs 2031200134 @default.
• W2031200134 citedByCount "41" @default.
• W2031200134 countsByYear W20312001342012 @default.
• W2031200134 countsByYear W20312001342013 @default.
• W2031200134 countsByYear W20312001342014 @default.
• W2031200134 countsByYear W20312001342015 @default.
• W2031200134 countsByYear W20312001342016 @default.
• W2031200134 countsByYear W20312001342017 @default.
• W2031200134 countsByYear W20312001342018 @default.
• W2031200134 countsByYear W20312001342019 @default.
• W2031200134 countsByYear W20312001342020 @default.
• W2031200134 countsByYear W20312001342021 @default.
• W2031200134 countsByYear W20312001342022 @default.
• W2031200134 countsByYear W20312001342023 @default.
• W2031200134 crossrefType "journal-article" @default.
• W2031200134 hasAuthorship W2031200134A5018012020 @default.
• W2031200134 hasAuthorship W2031200134A5035224025 @default.
• W2031200134 hasAuthorship W2031200134A5037329971 @default.
• W2031200134 hasAuthorship W2031200134A5044414244 @default.
• W2031200134 hasAuthorship W2031200134A5069535376 @default.
• W2031200134 hasAuthorship W2031200134A5071552059 @default.
• W2031200134 hasAuthorship W2031200134A5077895432 @default.
• W2031200134 hasAuthorship W2031200134A5085354660 @default.
• W2031200134 hasConcept C100402318 @default.
• W2031200134 hasConcept C115624301 @default.
• W2031200134 hasConcept C121332964 @default.
• W2031200134 hasConcept C146477669 @default.
• W2031200134 hasConcept C147789679 @default.
• W2031200134 hasConcept C149288129 @default.
• W2031200134 hasConcept C159467904 @default.
• W2031200134 hasConcept C166950319 @default.
• W2031200134 hasConcept C178790620 @default.
• W2031200134 hasConcept C185592680 @default.
• W2031200134 hasConcept C2781060337 @default.
• W2031200134 hasConcept C3288061 @default.
• W2031200134 hasConcept C32909587 @default.
• W2031200134 hasConcept C521692839 @default.
• W2031200134 hasConcept C547737533 @default.
• W2031200134 hasConcept C8010536 @default.
• W2031200134 hasConcept C97355855 @default.
• W2031200134 hasConceptScore W2031200134C100402318 @default.
• W2031200134 hasConceptScore W2031200134C115624301 @default.
• W2031200134 hasConceptScore W2031200134C121332964 @default.
• W2031200134 hasConceptScore W2031200134C146477669 @default.
• W2031200134 hasConceptScore W2031200134C147789679 @default.
• W2031200134 hasConceptScore W2031200134C149288129 @default.
• W2031200134 hasConceptScore W2031200134C159467904 @default.
• W2031200134 hasConceptScore W2031200134C166950319 @default.
• W2031200134 hasConceptScore W2031200134C178790620 @default.
• W2031200134 hasConceptScore W2031200134C185592680 @default.
• W2031200134 hasConceptScore W2031200134C2781060337 @default.
• W2031200134 hasConceptScore W2031200134C3288061 @default.
• W2031200134 hasConceptScore W2031200134C32909587 @default.
• W2031200134 hasConceptScore W2031200134C521692839 @default.
• W2031200134 hasConceptScore W2031200134C547737533 @default.
• W2031200134 hasConceptScore W2031200134C8010536 @default.
• W2031200134 hasConceptScore W2031200134C97355855 @default.
• W2031200134 hasIssue "11" @default.

• next