Matches in SemOpenAlex for { <https://semopenalex.org/work/W2031229809> ?p ?o ?g. }
- W2031229809 endingPage "2713" @default.
- W2031229809 startingPage "2713" @default.
- W2031229809 abstract "Reaction of [Os(por)O2][por = 5,10,15,20-tetra(p-tolyl)porphyrinate (ttp) or 2,3,7,8,12,13,17,18-octaethylporphyrinate (oep)] with thionyl chloride gave [Os(por)Cl2] in good yields. The dichloride compounds are paramagnetic with µeffca.2.7 µB and display temperature-independent contact-shifted 1H NMR spectra. Reaction of [Os(por)Cl2] with an excess of LiR (R = Ph or Me3SiCH2) gave air-stable diamagnetic dialkyl compounds [Os(por)R2]. The structure of [Os(ttp)(CH2SiMe3)2] has been established by X-ray crystallography. Cyclic voltammograms of the diphenyl compounds exhibit reversible metal-centred OsV–OsIV and OsIV–OsIII couples. Treatment of [Os(ttp)Ph2] with CeIV or AgBF4 afforded the diphenylosmium(V) compound [Os(ttp)Ph2]BF4, which is paramagnetic with µeffca. 1.7 µB." @default.
- W2031229809 created "2016-06-24" @default.
- W2031229809 creator A5003861735 @default.
- W2031229809 creator A5017955193 @default.
- W2031229809 creator A5019246193 @default.
- W2031229809 creator A5076236175 @default.
- W2031229809 date "1994-01-01" @default.
- W2031229809 modified "2023-10-18" @default.
- W2031229809 title "Synthesis and electrochemistry of dialkylosmium-(IV) and -(V) porphyrins. Crystal structure of [Os(ttp)(CH2SiMe3)2][H2ttp = 5,10,15,20-tetra(p-tolyl)porphyrin]" @default.
- W2031229809 cites W1965023349 @default.
- W2031229809 cites W1972400761 @default.
- W2031229809 cites W1975215694 @default.
- W2031229809 cites W1982760629 @default.
- W2031229809 cites W1985465044 @default.
- W2031229809 cites W1986155225 @default.
- W2031229809 cites W1986863341 @default.
- W2031229809 cites W1990986807 @default.
- W2031229809 cites W2007268362 @default.
- W2031229809 cites W2013889011 @default.
- W2031229809 cites W2020502440 @default.
- W2031229809 cites W2027977489 @default.
- W2031229809 cites W2033345547 @default.
- W2031229809 cites W2039444321 @default.
- W2031229809 cites W2068748515 @default.
- W2031229809 cites W2076156846 @default.
- W2031229809 cites W2088474661 @default.
- W2031229809 cites W2093530995 @default.
- W2031229809 cites W2299602266 @default.
- W2031229809 doi "https://doi.org/10.1039/dt9940002713" @default.
- W2031229809 hasPublicationYear "1994" @default.
- W2031229809 type Work @default.
- W2031229809 sameAs 2031229809 @default.
- W2031229809 citedByCount "17" @default.
- W2031229809 countsByYear W20312298092012 @default.
- W2031229809 countsByYear W20312298092019 @default.
- W2031229809 countsByYear W20312298092020 @default.
- W2031229809 countsByYear W20312298092022 @default.
- W2031229809 crossrefType "journal-article" @default.
- W2031229809 hasAuthorship W2031229809A5003861735 @default.
- W2031229809 hasAuthorship W2031229809A5017955193 @default.
- W2031229809 hasAuthorship W2031229809A5019246193 @default.
- W2031229809 hasAuthorship W2031229809A5076236175 @default.
- W2031229809 hasConcept C115260700 @default.
- W2031229809 hasConcept C115624301 @default.
- W2031229809 hasConcept C121332964 @default.
- W2031229809 hasConcept C124712363 @default.
- W2031229809 hasConcept C147789679 @default.
- W2031229809 hasConcept C155647269 @default.
- W2031229809 hasConcept C17525397 @default.
- W2031229809 hasConcept C178790620 @default.
- W2031229809 hasConcept C185592680 @default.
- W2031229809 hasConcept C2776942435 @default.
- W2031229809 hasConcept C2777873363 @default.
- W2031229809 hasConcept C2778695967 @default.
- W2031229809 hasConcept C2779480358 @default.
- W2031229809 hasConcept C52859227 @default.
- W2031229809 hasConcept C544153396 @default.
- W2031229809 hasConcept C62520636 @default.
- W2031229809 hasConcept C71240020 @default.
- W2031229809 hasConcept C75473681 @default.
- W2031229809 hasConcept C8010536 @default.
- W2031229809 hasConcept C96026104 @default.
- W2031229809 hasConceptScore W2031229809C115260700 @default.
- W2031229809 hasConceptScore W2031229809C115624301 @default.
- W2031229809 hasConceptScore W2031229809C121332964 @default.
- W2031229809 hasConceptScore W2031229809C124712363 @default.
- W2031229809 hasConceptScore W2031229809C147789679 @default.
- W2031229809 hasConceptScore W2031229809C155647269 @default.
- W2031229809 hasConceptScore W2031229809C17525397 @default.
- W2031229809 hasConceptScore W2031229809C178790620 @default.
- W2031229809 hasConceptScore W2031229809C185592680 @default.
- W2031229809 hasConceptScore W2031229809C2776942435 @default.
- W2031229809 hasConceptScore W2031229809C2777873363 @default.
- W2031229809 hasConceptScore W2031229809C2778695967 @default.
- W2031229809 hasConceptScore W2031229809C2779480358 @default.
- W2031229809 hasConceptScore W2031229809C52859227 @default.
- W2031229809 hasConceptScore W2031229809C544153396 @default.
- W2031229809 hasConceptScore W2031229809C62520636 @default.
- W2031229809 hasConceptScore W2031229809C71240020 @default.
- W2031229809 hasConceptScore W2031229809C75473681 @default.
- W2031229809 hasConceptScore W2031229809C8010536 @default.
- W2031229809 hasConceptScore W2031229809C96026104 @default.
- W2031229809 hasIssue "18" @default.
- W2031229809 hasLocation W20312298091 @default.
- W2031229809 hasOpenAccess W2031229809 @default.
- W2031229809 hasPrimaryLocation W20312298091 @default.
- W2031229809 hasRelatedWork W102052830 @default.
- W2031229809 hasRelatedWork W1979589389 @default.
- W2031229809 hasRelatedWork W1993508825 @default.
- W2031229809 hasRelatedWork W2069192433 @default.
- W2031229809 hasRelatedWork W2076781139 @default.
- W2031229809 hasRelatedWork W2383321051 @default.
- W2031229809 hasRelatedWork W2587384573 @default.
- W2031229809 hasRelatedWork W3114366769 @default.
- W2031229809 hasRelatedWork W3124267002 @default.
- W2031229809 hasRelatedWork W322788294 @default.
- W2031229809 isParatext "false" @default.
- W2031229809 isRetracted "false" @default.