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- W2031248872 abstract "An enantioselective synthesis of the ABC-tricyclic furanochroman core of phomactin A has been accomplished by a γ-hydroxylation approach. The C ring was established by γ-hydroxylation of an α-enone. The regioselectivity was optimized by using a strong base with an oxophilic cation (t-BuLi) and a bulky oxygen donor (Davis reagent), which afforded the γ-hydroxylation product selectively in 63% yield." @default.
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- W2031248872 date "2015-04-10" @default.
- W2031248872 modified "2023-10-07" @default.
- W2031248872 title "Enantioselective Synthesis of the ABC-Tricyclic Core of Phomactin A by a γ-Hydroxylation Strategy" @default.
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- W2031248872 doi "https://doi.org/10.1021/acs.orglett.5b00586" @default.
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