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• W2031254469 abstract "Pinus radiata kraft pulps with varying carboxyl content were studied using Fourier transform infrared photoacoustic spectroscopy (FT-IR-PAS). The examined pulp samples, with Kappa number ranging from 20.8 to 128, originated from pulping experiments conducted in flow-through reactors utilizing varying effective alkali, temperature, and cooking time. A partial least-squares (PLS) analysis was used to formulate a model that correlates the spectral data with the carboxyl content of pulp. Using three principal components, the resultant PLS model could explain approximately 98.5% of the variance in the X-matrix (spectral features) and 96.8% of the variance in the Y-matrix (measured carboxyl content). The FT-IR-PAS technique in combination with PLS analysis predicts the carboxyl content of the pulps with a high degree of accuracy. This method is much faster than the conventional titration methods and also not destructive to the pulp sample." @default.
• W2031254469 created "2016-06-24" @default.
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• W2031254469 date "2006-08-23" @default.
• W2031254469 modified "2023-09-24" @default.
• W2031254469 title "Determination of Carboxyl Content in High-Yield Kraft Pulps Using Photoacoustic Rapid-Scan Fourier Transform Infrared Spectroscopy" @default.
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• W2031254469 doi "https://doi.org/10.1021/ac0605952" @default.
• W2031254469 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/17007501" @default.
• W2031254469 hasPublicationYear "2006" @default.
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