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• W2031291712 abstract "A population balance model was developed to simulate simultaneous precipitation and flocculation during precipitative softening. Rate coefficients for nucleation, crystal growth, and flocculation were extracted from experimental particle-size distribution (PSD) data based on changes in the total number and total volume of particles. Three models of flocculation were evaluated: rectilinear, curvilinear, and an empirical size-independent model. Model simulations were compared with experimental PSD data to test which model was most appropriate. The curvilinear precipitative flocculation model was superior when seeded precipitation occurred at moderate mixing intensities (G=50–100 s−1). However, the curvilinear model overpredicts the formation of very large particles and requires values of the collision efficiency greater than 1.0, suggesting a more complicated dependence of the PSD dynamics on mixing intensity and saturation ratio than presently included in the model. At higher mixing intensities (G=300 s−1), flocculation exhibited size-independent behavior, indicating that physical/chemical aspects of the precipitation process are altering or overshadowing the physics described in the curvilinear flocculation model." @default.
• W2031291712 created "2016-06-24" @default.
• W2031291712 creator A5012192020 @default.
• W2031291712 creator A5051500859 @default.
• W2031291712 date "2010-01-01" @default.
• W2031291712 modified "2023-10-16" @default.
• W2031291712 title "Modeling Particle-Size Distribution Dynamics during Precipitative Softening" @default.
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• W2031291712 doi "https://doi.org/10.1061/(asce)ee.1943-7870.0000127" @default.
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