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• W2031293828 abstract "Solid-liquid phase behavior of binary mixture of nonionic surfactant, tetraethylene glycol decyl ether (C10E4), and water was examined by means of differential scanning calorimetry (DSC), Fourier transform infrared spectroscopy (FT-IR), polarized optical microscopy (POM), and visual observation in the temperature range −40–70°C. The DSC experiments allowed us to determine many phase boundaries among various phases appearing in this mixture system, including mesomorphic phases. TheT-Xphase diagram for fluid phases of C10E4/H2O mixture constructed from the results of DSC and visual observation was in good agreement with that previously reported by Lang and Morgan for the same mixture system except for the occurrence of a dilute lamellar phase (Lang, J. C. and Morgan, R. D., J. Chem. Phys., 73, 5849 (1980). The FT-IR spectra obtained for the mixture in a solid state demonstrated that the phase compound expressed by C10E4· 6H2O is formed in the solid phase, which indicates that there is a strong interaction in the solid state between water and the hydrophilic polyoxyethylene chain of the surfactant. The FT-IR results also suggested that the strength of the hydrogen bond between water and the polyoxyethylene chain of C10E4differs among the phase states of the mixture, and increases in the orderL2<L1<Lα≈H1< solid, whereL2refers to the inverted micellar phase,L1the normal micellar phase,Lαthe lamellar phase, andH1the normal hexagonal phase." @default.
• W2031293828 created "2016-06-24" @default.
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• W2031293828 creator A5032709542 @default.
• W2031293828 date "1998-09-01" @default.
• W2031293828 modified "2023-10-18" @default.
• W2031293828 title "Solid-Liquid Phase Behavior of Binary Mixture of Tetraethylene Glycol Decyl Ether and Water" @default.
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• W2031293828 doi "https://doi.org/10.1006/jcis.1998.5615" @default.
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