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• W2031318465 startingPage "1748" @default.
• W2031318465 abstract "The occurrence of Yb ions in two charge states (trivalent and divalent) in ZnS is proved with use of the photostimulated electron-paramagnetic-resonance technique. ${mathrm{Yb}}^{2+}$ is found to form a deep hole-trap center with energy level located at 1.65ifmmodepmelsetextpmfi{}0.05 eV below the bottom of the ZnS conduction band. Efficient ${mathrm{Yb}}^{3+}$ intrashell luminescence is observed under excitation in the region of the valence band to ${mathrm{Yb}}^{2+}$ photoionization transition. Indirect recombination of a deep Yb-bound exciton with energy transfer to the 4f shell of ${mathrm{Yb}}^{3+}$ is proposed to explain the photoluminescence excitation spectrum. Tentative assignment of the observed broad emission band with the maximum at 10 800 ${mathrm{cm}}^{mathrm{ensuremath{-}}1}$ to direct Yb-bound excitation recombination is suggested." @default.
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• W2031318465 date "1989-07-15" @default.
• W2031318465 modified "2023-10-18" @default.
• W2031318465 title "Recombination processes in Yb-activated ZnS" @default.
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• W2031318465 doi "https://doi.org/10.1103/physrevb.40.1748" @default.
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