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- W2031335185 abstract "Abstract β-alkylamino-sulphone hydrochloride and methiodide derivatives react quantitatively with thiophenols, leading to the replacement of the alkylamino residue with the aryl-mercapto group. Kinetic data indicate that the reaction proceeds through an elimination-addition mechanism, involving a pre-equilibrium for hydrochlorides. For the two classes of compounds, different elimination mechanisms are suggested: an intramolecular one for hydrochlorides and a E2 type mechanism, with a partially carbanionic character for methiodide derivatives. The observed reactivity of both systems is then compared with that of the corresponding carbonyl compounds." @default.
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- W2031335185 date "1970-01-01" @default.
- W2031335185 modified "2023-09-27" @default.
- W2031335185 title "Reactivity of β-alkylamino-sulphonyl compounds towards thiophenols" @default.
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- W2031335185 doi "https://doi.org/10.1016/s0040-4020(01)98770-8" @default.
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