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- W2031364815 abstract "Recently, there has been some controversy over whether the first step in methanol oxidation on platinum is the transfer of a hydrogen i.e.: 13CH316OH(ad)+18O(ad)→13CH316O(ad)+18O(ad)H or a methyl group i.e.: 13CH316OH(ad)+18O(ad)→16OH(ad)+13CH318O(ad). In this paper, we use isotopic substitutions to show that the O–H bond breaks rather than the C–O bond, even though in the gas phase, the O–H bond is 20 kcal mol−1 stronger than the C–O bond. These results are consistent with our understanding of intrinsic barriers." @default.
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- W2031364815 date "1998-12-01" @default.
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- W2031364815 title "Methanol oxidation on (2×1)Pt(110): does the C–O or O–H bond break first?" @default.
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- W2031364815 doi "https://doi.org/10.1016/s0039-6028(98)00761-4" @default.
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