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• W2031422702 abstract "The 351 nm photoelectron spectra of OH−(NH3)n n=1,2 and the deuterated analogs exhibit two broad peaks. Ab initio calculations of the anion and neutral potential-energy surfaces have been carried out using an MP2 (second-order Mo/ller–Plesset)/6-31++G** basis set. The geometries, frequencies, and energetics from these calculations aid in the interpretation of the experimental results. An estimate of the OH(NH3) electron affinity is 2.35±0.07 eV based on experimental and theoretical results. Calculations of the anion vibrational wave functions indicate that following electron photodetachment, the neutral potential-energy surface is accessed from the reactant entrance channel through the transition state region." @default.
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• W2031422702 date "2000-03-15" @default.
• W2031422702 modified "2023-09-26" @default.
• W2031422702 title "Negative ion photoelectron spectroscopy of OH−(NH3)" @default.
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• W2031422702 doi "https://doi.org/10.1063/1.481051" @default.
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