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- W2031445878 abstract "The crystal and magnetic structures of CsCoF4 have been determined by means of neutron powder diffraction. The crystal structure is isostructural with β-RbAlF4 and can be described as the stacking of unconnected tetragonal tungsten bronze type layers with Cs+ cations in between. The strong anisotropy of 3d6 Co3+ spins is responsible for a collinear magnetic structure, despite the presence of magnetic frustration. The competition between antiferromagnetic superexchange interactions within the triangular cycles of the structure is solved by the break of the weakest interaction, resulting in a parallel arrangement of spins connected by the AF interaction. This situation is compared with the one previously observed in KMnFeF6 which exhibits a similar frustrating topology, but with isotropic interactions." @default.
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- W2031445878 date "1991-07-01" @default.
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- W2031445878 title "Ordered magnetic frustration: XVI. Magnetic structure of CsCoF4 at 1.5 K" @default.
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- W2031445878 doi "https://doi.org/10.1016/0022-4596(91)90271-i" @default.
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