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• W2031472850 abstract "The crystal-chemistry of a series of synthetic Al–Fe3 + smectites was studied in detail using near and mid infrared spectroscopy. Chemical and NIR data indicated a quite complete range of octahedral Al for Fe3 + substitution, and therefore, the solid-solution between beidellite and nontronite end-members was continuous and complete. The wavenumbers of several infrared absorption bands were correlated with the chemistry of the synthetic smectites, providing a useful tool to constrain their structural formulae and also for assisting in assignments of similar bands in natural smectites. The Al and Fe3 + cations were shown to be randomly distributed in the octahedral sheet of synthesized smectites. Despite the high availability of iron during synthesis, generally only a small amount of tetrahedral Fe3 + was observed." @default.
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• W2031472850 date "2015-02-01" @default.
• W2031472850 modified "2023-10-13" @default.
• W2031472850 title "Hydrothermal synthesis of dioctahedral smectites: The Al–Fe3+ chemical series. Part II: Crystal-chemistry" @default.
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• W2031472850 doi "https://doi.org/10.1016/j.clay.2014.11.014" @default.
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