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- W2031479080 abstract "1 A new synthesis of R- and S-acetic acid (R- and S-[2H1, 3H1]acetate) is described. 2 R-Acetic acid after conversion into citrate on si-citrate synthase and cleavage of the citrate with citrate lyase regenerates an acetate which is still predominantly R. 3 S-Acetic acid when put through the same sequence yields acetic acid which is predominantly S. 4 Essentially the same results as in (2) and (3) are obtained when ATP-citrate lyase is substituted for citrate lyase. 5 The conclusion is drawn that on si-citrate synthase, the replacement of hydrogen by oxaloacetic acid proceeds with inversion of configuration at the methyl group. 6 It also follows that ATP-citrate lyase, like citrate lyase, cleaves citrate with inversion of configuration. 7 It is further deduced that there is a normal intramolecular deuterium-isotope effect, with respect to the chiral-methyl group, in the condensation of chiral acetate with oxaloacetate on si-citrate synthase." @default.
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- W2031479080 date "1971-12-01" @default.
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- W2031479080 title "Stereochemistry of si-Citrate Synthase and ATP-Citrate-Lyase Reactions" @default.
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- W2031479080 doi "https://doi.org/10.1111/j.1432-1033.1971.tb19672.x" @default.
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