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- W2031502253 abstract "The complex [(IMesH2)(PPh2Cy)Cl2RuCHPh] was synthesised and shown to be an active catalyst in ring-closing metathesis of a diallylmalonate. Its phosphine exchange was investigated in C6D6 using magnetisation transfer 31P NMR spectroscopy and it was found to operate via a dissociative mechanism with k353 = 4.1 ± 0.9 s−1, ΔH‡ = 84 ± 10 kJ mol−1 and ΔS‡ = 4 ± 28 J mol−1 K−1." @default.
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- W2031502253 date "2007-11-01" @default.
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- W2031502253 title "Kinetic investigation of a ruthenium metathesis catalyst" @default.
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- W2031502253 doi "https://doi.org/10.1016/j.jorganchem.2007.08.033" @default.
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