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- W2031505713 abstract "The effect of the aqueous solution pH and ligand type (H2PO-4, HPO2-4, H2CO3, HCO-3 Cl-, and ClO-4) on acridine adsorption to silica was studied in a series of continuous-flow column experiments. The extent of acridine adsorption at solution pH's above its pKa was enhanced when H2CO3/HCO-3 was used as a buffer rather than H2PO-4/HPO2-4, due to more exothermic hydration enthalpy of the H2CO3/HCO-3 buffer. The greater polarity of the acridinium cation and/or acridinium cation/ligand complexes at solution pH's below the pKa of acridine minimized the effect of differences in ligand hydration enthalpies on acridine adsorption. These results suggest that acridine mobility in groundwater would be buffer dependent." @default.
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- W2031505713 date "1994-11-01" @default.
- W2031505713 modified "2023-09-26" @default.
- W2031505713 title "Dependence of Acridine Adsorption on Ligand Hydration Enthalpy" @default.
- W2031505713 doi "https://doi.org/10.1006/jcis.1994.1393" @default.
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