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- W2031510233 abstract "Abstract Unsupported and supported Nd(C3H5)3·dioxane and La(C3H5)3·1.5 dioxane complexes were investigated by diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS), Raman spectroscopy and temperature-programmed reaction spectroscopy (TPRS). The obtained results allow conclusions concerning the structure and thermal stability of metal complexes, as well as their bonding properties. A structural model was developed for such allyl compounds based mainly on the vibrational spectroscopy data. This model was used to interpret the structural changes of these allyl–lanthanide complexes after being supported on methylaluminoxan (MAO)-modified silica (WITCO)." @default.
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- W2031510233 date "2000-11-01" @default.
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- W2031510233 title "DRIFTS and NIR Raman investigations on unsupported and supported allyl–lanthanoid complexes — catalysts for the polymerization of butadiene" @default.
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