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- W2031510764 abstract "In this work, the crystalline environment of DyTiFe1 1-xCox is studied by 57Fe Mossbauer spectroscopy. Results indicate that Co prefers to occupy 8f site and Ti prefers 8i site. For rare earth- transition based compounds, we suggest one experimental rule which gives a general description on the tendency of the preferential occupation of the transition elements on transition type crystalline sites in such compounds: Transition atom with smaller atomic number or with smaller number of d electrons has a preferential tendency to occupy the site with larger transition-transition distance; meanwhile the transition atom with the large atomic number prefers to occupy the transition sites with relative short transition-transition distance. Besides it seems that we can treat Al like a quisi-transition at atom with the atomic number smaller than that of Cr when Al participates in substitution in rare earth - transition based compounds." @default.
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- W2031510764 date "1993-01-01" @default.
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- W2031510764 title "Tendency of preferential occupation of transition elements on crystalline sites in rare earth - transition based compounds" @default.
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- W2031510764 doi "https://doi.org/10.1016/0038-1098(93)90433-n" @default.
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