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- W2031549429 abstract "An ${mathrm{Fe}}^{+}$-type center with axial 〈001〉 symmetry has been studied by electron nuclear double resonance (ENDOR) in the microwave X and Q bands. The ${mathrm{Fe}}^{+}(mathrm{I})$ center is produced only after irradiation with x or ensuremath{gamma} rays at 80 K of ${mathrm{SrCl}}_{2}{:mathrm{F}mathrm{e}}^{2+}$ crystals grown in a ${mathrm{Cl}}_{2}$ atmosphere. It has a ${3d}^{7}{}^{4}F{ensuremath{Gamma}}_{8}$ ground state with spin $S=frac{3}{2}.$ As shown by the correlated analysis of the ENDOR data and electron paramagnetic resonance superhyperfine structure, the ${mathrm{Fe}}^{+}$ ion is situated in the center of a tetragonally compressed cube of eight nearest ${mathrm{Cl}}^{mathrm{ensuremath{-}}}$ ions. The simplest model of the ${mathrm{Fe}}^{+}(mathrm{I})$ center, compatible with the magnetic resonance results, consists of an interstitial ${mathrm{Fe}}^{+}$ ion with two substitutional monovalent cations, very likely ${mathrm{K}}^{+}$ ions, in two opposite nearest-neighbor ${mathrm{Sr}}^{2+}$ sites along the tetragonal axis of the center." @default.
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- W2031549429 date "2001-06-11" @default.
- W2031549429 modified "2023-09-24" @default.
- W2031549429 title "Magnetic resonance study of theFe+(I)center inSrCl2single crystals" @default.
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- W2031549429 doi "https://doi.org/10.1103/physrevb.64.024405" @default.
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