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- W2031557051 abstract "The rate constants for the gas-phase reactions of phenanthrene, phenanthrene-d10, and 1-, 2-, 3-, and 9-methylphenanthrenes with the hydroxyl radical were measured using the relative rate technique over the temperature range of 323−403 K and at a total pressure of 760 Torr. On-line mass spectrometry was used to monitor the concentrations of reactants as a function of time. The following Arrhenius expressions have been determined for these reactions (in units of cubic centimeters per molecule per second): ( ) × 10-12 exp[(477 ± 89)/T] for phenanthrene, ( ) × 10-12 exp[(745 ± 301)/T] for phenanthrene-d10, ( ) × 10-12 exp[(1420 ± 242)/T] for 1-methylphenanthrene, ( ) × 10-12 exp[(964 ± 322)/T] for 2-methylphenanthrene, ( ) × 10-12 exp[(926 ± 77)/T] for 3-methylphenanthrene, and ( ) × 10-12 exp[(679 ± 372)/T] for 9-methylphenanthrene. The Arrhenius parameters determined here for phenanthrene-d10 and 1-, 2-, 3-, and 9-methylphenanthrene are the first to be reported." @default.
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- W2031557051 date "2003-08-01" @default.
- W2031557051 modified "2023-10-18" @default.
- W2031557051 title "Rate Constants for the Gas-Phase Reactions of Methylphenanthrenes with OH as a Function of Temperature" @default.
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- W2031557051 doi "https://doi.org/10.1021/jp034159k" @default.
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