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• W2031567862 abstract "The association process of a host–guest system, cyclodextrins (CyD) – 3-carboxycoumarin acid (3CCA) was followed by means of UV–vis, circular dichroism and steady-state fluorescence spectroscopies in buffer solution at pH = 1. The experimental data were analyzed in order to get information on the stoichiometry, the equilibrium constants and the geometry of the inclusion complexes. In the circular dichroism spectra, a positive induced signal was obtained reflecting that the guest penetrates the cavity in such a way that the transition moment of the electronic band is quasi parallel to the host main axis. The experimental data are supported by the DFT and TDDFT (B3LYP/6-31G) calculations performed on the isolated ligand and by TDDFT (ZINDO) calculations carried out on the supramolecular ligand-cyclodextrin system." @default.
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• W2031567862 date "2012-06-01" @default.
• W2031567862 modified "2023-09-26" @default.
• W2031567862 title "Experimental and theoretical study of the inclusion complexes of 3-carboxycoumarin acid with β- and 2-hydroxypropyl-β-cyclodextrins" @default.
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• W2031567862 doi "https://doi.org/10.1016/j.saa.2012.02.027" @default.
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