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- W2031575962 abstract "Abstract The presence of rotational disorder in the plastic phase of sulfolane, stable within 15.45 and 28.45 C, has been demonstrated by X-ray diffraction techniques. Sulfolane forms. hexagonal crystals with unit-cell parameters a = b = 6.05(1), c = 9.75(1) Å and two molecules per unit cell. The molecules are randomly oriented about the positions (⅓ ⅔ ¼) and (⅔ ⅓ ¾) giving rise to a hexagonal close-packed structure. By using a relatively coarse molecular model the experimental diffraction amplitudes are accounted for within an error of 16% by the assumption of a wholly random orientation. Data strongly substantiate the conclusions arising from previous thermodynamic studies." @default.
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- W2031575962 date "1983-01-01" @default.
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- W2031575962 title "X-ray Diffraction Study of Mesomeric Plastic Phase of Sulfolane Whose Stability Domain Ranges Within 15.45 and 28.45 C" @default.
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- W2031575962 doi "https://doi.org/10.1080/00268948308083072" @default.
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