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- W2031610894 abstract "For the purpose of measuring kinetic data for the oxidative thermal degradiation reaction, Kissinger's relation was applied to 10 commercial thermoplastic resins. When these contain hydrogen as a constituent, in general, they give rise to an exothermic oxidation reaction and begin to decompose, in the presence of oxygen, at a temperature slightly less than 200°C. Their E values were mostly from 10 to 20 kcal/mole. A compensation effect was observed in which In A increased with an increase in E. Evidently, an oxidation reaction occurs at the surface of molten plastics prior to the thermal degradation. The coexistence of trace amounts of water with plastics was found to play a part in lowering the activation energy of this reaction. It was concluded that the activation energy of the oxidative thermal degradation could express well the relationship between the molecular structure and its behavior when heated, and could be used as a guide in the search for heat-resistant plastics." @default.
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- W2031610894 date "1972-11-01" @default.
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- W2031610894 title "Activation energy for the oxidative thermal degradation of plastics" @default.
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- W2031610894 doi "https://doi.org/10.1016/0040-6031(72)80018-2" @default.
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