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• W2031616167 abstract "The Schiff base ligands, 2-hydroxy-N-cyclohexyl-l-naphthaldimine (I), and 3-hydroxy-N-cyclohexyl-2-naphthaldimine (II), and their corresponding CuII complexes (1–2) respectively were synthesized and characterized. The crystal and molecular structures of bis-{(cyclohexyl)[(2-oxo-1H-naphth-1-ylidene)-methyl]aminato}copper(II) (1) and bis-{(cyclohexyl)[(3-oxo-2H-naphth-2-ylidene)-methyl]aminato} copper(II) (2), were determined. The X-ray diffraction study shows that the geometry around the metal atom for (1), is stepped square planar with a step of 1.063 Å while for (2), the geometry around the metal atom for square planar with an angle between the coordination planes O(1)CuN(1) and O(1a)CuN(1a) of 39.9°. Electrochemical studies show a dependence of the CuII/CuI potentials on the ligand structure." @default.
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• W2031616167 date "1997-10-01" @default.
• W2031616167 modified "2023-09-27" @default.
• W2031616167 title "The crystal structures and electrochemical studies of two naphthalenic Schiff base copper(II) complexes" @default.
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• W2031616167 doi "https://doi.org/10.1016/s0277-5387(97)00200-3" @default.
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